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AG111 - MATERIAL SAFETY DATA
SHEETS - Part A Material Safety Data Sheet
Revised 6/00
Section I
Manufacturer's Name
Emergency
Telephone #
PM Industries
1-800-833-8933
Address
Non-Emergency
Telephone #
442 Ridge Road
1-800-833-8933
West Milford, NJ 07480
Chemical Name & Synonyms
Trade Name and
Synonyms
Two Component Polyurethane Coating
AG111 PART A
Section II - Hazardous Ingredients
% %
TLV CAS#
U111,117 U111,117
Clear Pigmented
Solvents
Propylene Glycol 15.9 13.1 OSHA-Not
108-65-6
Monomethyl Ether
Established
Acetate (PMA) ACGIH-Not
Established
Exposure limits of 100 ppm TWA (150 ppm stel) are recommended based on
similarity to propylene glycol monomethyl ether.
Ethyl 3-Ethoxypro- OSHA
- Not
pionate(EEP) 45.3 12.5
Established 763-69-9
ACGIH-Not
Established
An exposure limit has not been established. Recommended exposure limit is 50
ppm as an 8 hour TWA and 100 ppm as a 15 minute stel.
Aromatics 100 6.2 OSHA:
150 ppm TWA 64742-95-6
200
ppm stel
ACGIH:
150 ppm TWA
200
ppm stel
Xylene 2.3 2.0 OSHA: 100 ppm TWA 1330-20-7
150
ppm STEL
ACGIH:
100 ppm TWA
150
ppm STEL
This document is prepared pursuant to the OSHA Hazard Communication Standard
(29 CFR 1910.1200). In addition, other substances not "hazardous" per this
OSHA standard may be listed.
Section III - Physical Data
Specific Gravity ------------U 111,117 Clear ----- 1.04
---U 111,117 Pigmented (Dependent upon color)- 1.1 to
1.5
% Volatile by Volume --------- Approximately 51 to 74.
Vapor Pressure ------------- PMA : 3.7 mm Hg. @ 20° C.
EEP:
l.lmmHg.@25°C.
Aromatics
100 : Less than 10 mm Hg. @ 25° C.
Xylene
: 9 mm Hg. @ 20° C.
Water Solubility ------------ None
Appearance & Odor -----------Clear or color of pigment/solvent odor
Section IV - Fire and Explosion Data
Flash Point ---------------108° F. TCC.
Flammable Limits: LEL (%) UEL (%)
PMA @ 173° F. 1.3 13.1
EEP
@190°F. 1.05 Not
Determined
Aromatics @ 283° F. 1.0 7.0
Xylene 1.0
7.0
Extinguishing Media: Dry chemical; carbon dioxide; foam; water
Special Fire Fighting Procedures:
Full emergency equipment with self contained breathing apparatus and full
protective clothing should be worn by fire fighters. During a fire, irritating
and/or toxic gases and smoke (see reactivity data) may be present from
decomposition/combustion. Isolate from heat, electrical equipment, sparks and
open flame. Closed container may explode when exposed to extreme heat. Use
cold water to cool fire exposed containers to minimize risk of rupture.
Solvent vapors may be heavier than air. Stagnant air may cause vapors to
accumulate and travel along
the ground to an ignition source which may result in a flash back to the
source of the vapors.
Section V - Human Health Data
Route of Entry: Inhalation; skin contact; eye contact.
Human Effects and Symptoms of Overexposure:
Acute Inhalation
Solvent vapors are irritating to the eyes, nose, throat and respiratory tract
resulting in red, itchy eyes, dryness of the throat and tightness in the
chest. Other possible symptoms of overexposure include headache, nausea,
narcosis, fatigue and loss of appetite.
Chronic Inhalation:
Chronic exposure to organic solvents has been associated with various
neurotoxic effects including permanent brain and nervous system damage.
Symptoms include: loss of memory, loss of intellectual ability and loss of
coordination.
Acute Skin Contact:
Repeated or prolonged skin contact with solvents can result in dry, defatted
and cracked skin causing increased susceptibility to infection. In addition,
skin irritation (i.e. redness, swelling), which may develop into dermatitis,
may occur from skin contact. Solvents can penetrate the skin and may cause
systemic effects similar to those identified under acute inhalation symptoms.
Chronic Skin Contact:
Chronic skin exposure to solvents may cause effects similar to those
identified under chronic inhalation effects.
Acute Eye Contact:
Liquid, aerosols and vapors of this product are irritating and can cause
tearing, reddening and swelling of the eye. If left untreated, corneal damage
can occur and injury is slow to heal. However, damage is usually reversible.
See Section VI for treatment.
Chronic Eye Contact:
Prolonged vapor contact may cause conjunctivitis.
Acute Ingestion:
Can result in irritation and possible corrosive action in the mouth, stomach
tissue and digestive tract. Vomiting may cause aspiration of the solvent
resulting in chemical pneumonitis.
Chronic Ingestion:
None found
Carcinogenicity
NTP -------- Not Listed
IARC ------- Not Listed
OSHA ------- Not Regulated
Medical conditions aggravated by exposure:
None Known
Exposure Limits:
Not established for product as a whole. Refer to Section II for exposure
limits of hazardous constituents.
Section VI - Emergency and First Aid Procedures
First Aid for Eyes:
Flush with clean, lukewarm water (low pressure) for at least 15 minutes, while
lifting eyelids. Obtain medical attention if irritation persists.
First Aid for Skin:
Remove contaminated clothing immediately. Wash affected areas thoroughly with
soap and water. Wash contaminated clothing thoroughly before reuse.
First Aid for Inhalation:
Move to an area free from risk of further exposure. Administer oxygen or
artificial respiration as needed. Obtain medical attention.
First Aid for Ingestion:
Do not induce vomiting. Do not give anything by mouth to an unconscious
person. Consult physician.
Section VII - Employee Protection Recommendations
Eye Protection Requirements:
Safety glasses, splash goggles or face shield. Contact lenses should not be
worn.
Skin Protection Requirements:
Chemical resistant gloves. Cover as much of the exposed skin area as possible
with appropriate clothing.
Respirator/Ventilation Requirements:
Exhaust ventilation sufficient to keep the airborne concentrations of the
solvents in the workplace below their respective TLVs. Respirator that is
recommended or approved for use in organic vapor containing environments (air
purifying or fresh air supplied) may be necessary. In spray applications an
organic vapor/particulate respirator or air supplied air unit is necessary.
The use of a positive pressure supplied air respirator is mandatory when;
airborne concentrations are not known; when levels are 10 times the
appropriate TLV; or if spraying is performed in a confined space or area with
limited ventilation. Take into account other materials being used
concurrently, the type of application and environmental concentrations when
selecting a respirator. Observe OSHA regulations for respirator use (29 CFR
1910.134).
Additional Protective Measures:
Safety showers and eyewash stations should be available. Educate and train
employees in safe use of product. Follow all label instructions.
Section VIII - Reactivity Data
Stability --------------- Stable under normal conditions.
Hazardous polymerization ------Will not occur.
Incompatibilities ------------ Strong Oxidizers.
This product contains trimethylol propane and should not be combined with
phosphorus containing materials because highly toxic fumes can be emitted in a
fire situation.
Instability Conditions --------- None Known.
Decomposition Products:
By Fire: CO, C02.
Section IX - Spill and Leak Procedures
Spill or Leak Procedures:
Evacuate nonessential personnel. Remove all sources of ignition and ventilate
the area. Equip clean up crew with appropriate protective equipment (see
employee protection recommendations). Soak up in absorbent material such as
sand, vermiculite, fuller's earth and collect material in suitable containers.
Waste Disposal Method:
Waste may be incinerated or disposed of in accordance with federal, state, and
local environmental control regulations. Empty containers must be handled with
care due to product residue and combustible solvent vapor. Do not heat or cut
empty container with electric or gas torch, (see Sections IV and VIII).
Section X - Special Precautions and Storage Data
Storage Temperature (min/max) ----- 32° F. (0 C)/122° F. (50 C)
Shelf Life ----------------- Two years, if unopened.
Special sensitivity:
Material is hygroscopic and may absorb small amount of atmospheric moisture.
Containers should be tightly closed to prevent contamination with foreign
materials and moisture.
Handling/storage precautions:
Material is combustible - keep away from heat, sparks and open flame. Take
precautions against the buildup of electrostatic charges. Store in tightly
closed containers to prevent moisture contamination. Practice caution and good
personal cleanliness to avoid contact with skin and eyes. Avoid breathing
vapors.
Note: Two component system- the cautions and hazards of both components apply
to combined product when mixed.
Section XI - Shipping Information
D.O.T. Shipping Name --------Paint
D.O.T. Hazard Class -------- 3
UN/NA Number---------UN 1263
Packaging Group~----------III
D.O.T. Label -------------Combustible *
D.O.T. Placard ------------ Combustible *
*If quantity is in a non bulk packaging (less than 119 gallons), this material
ships as non regulated unless the combustible liquid is a hazardous substance
or a hazardous waste.
IMO/IMDG
ICAO/IATA
Hazard Label--------------Flammable Liquid
Hazard Placard-------------Flammable Liquid
Section XII - Federal Regulatory Information
OSHA status: This product is hazardous under the criteria of the Federal OSHA
Hazard
Communication Standard 29 CFR 1910.1200.
TSCA status: on TSCA inventory
SARA Title III:
Section 302 Extremely Hazardous Substances: None
Section 311/312 Hazard Categories: Immediate Health Hazard
Delayed
Health Hazard
Fire Hazard
Section 313 Toxic Chemicals: Aromatics 100 (CAS # 64742-95-6)
Xylene (CAS#
1330-20-7)
Notice: This information is presented in good faith and believed to be
accurate as of the effective date below. However, no warranty is expressed or
implied regarding the accuracy of this data or the results to be obtained from
the use thereof. PM Industries assumes no responsibility for personal injury
or property damage to vendees, users or third parties caused by the material,
such vendees or users assume all risks associated with the use of the
material.
Regulatory requirements are subject to change and may differ from one location
to another; it is the buyer's responsibility to ensure that its activities
comply with federal, state and local laws. The preceding specific information
is made for the purpose of complying with numerous federal, state and local
laws and regulations.
7/96,Rev 7/98
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